期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 4, 页码 623-626出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09178e
关键词
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资金
- National Natural Science Foundation of China [21672174, 21977084]
- Natural Science Foundation of Chongqing [cstc2019jcyj-msxmX0297]
A highly enantioselective and direct synthesis of C2-quaternary indolin-3-ones from 2-arylindoles by combining electrochemistry and organocatalysis is described. Excellent enantioselectivities (up to 99% ee) and diastereoselectivities (>20 : 1) can be obtained through anodic oxidation in combination with asymmetric proline-catalyzed alkylation in an undivided cell under constant-current conditions.
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