期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 4, 页码 603-606出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08550e
关键词
-
资金
- National Science Foundation [CHE-1566258]
Cyclic voltammetry reveals that aqueous trans-[Cr(cyclam)Cl-2](+) is reversibly reduced at a mercury electrode, with a small prewave suggesting an adsorptive interaction between the complex and electrode surface. A catalytic current is observed in the presence of excess nitrate, with the onset potential for catalysis at the prewave. Nitrate is electrocatalytically reduced to nitrite, with preliminary mechanistic investigations implicating a chromium oxo intermediate.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据