期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 18, 期 4, 页码 642-645出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02625h
关键词
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资金
- National Natural Science Foundation of China [41906106, 31272087]
- Pearl River Science and Technology New Star Fund of Guangzhou [201806010080]
- GDAS' Project of Science and Technology Development [2019GDASYL-0103007]
- Science and Technology Program of Guangzhou [201607020018]
- Natural Science Foundation of Guangdong Province [2016A030312014]
Photeroids A (1) and B (2), two structurally fascinating meroterpenoids, were isolated from the deep-sea-derived fungus Phomopsis tersa FS441. Their structures were sufficiently established by a comprehensive interpretation of the spectroscopic data, NMR spectra, and ECD calculation. Photeroids A and B represented the first phenolic sesquiterpene meroterpenoids featuring a highly fused 6/6/6/6 tetracyclic ring system derived through a rarely-occurring hetero-Diels-Alder reaction via an orthoquinone methide intermediate. Additionally, they were also evaluated for their cytotoxic activities against four human cancer cells, wherein compounds 1 and 2 exhibited moderate cytotoxic activities.
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