期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 487, 期 -, 页码 266-280出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2016.10.043
关键词
Cellulose trimellitate; Competitive adsorption; Metal ion; Multicomponent; IAST; RAST
资金
- Universidade Federal de Ouro Preto (UFOP) [23109.003753/2015-59]
- Fundacao de Amparo a Pesquisa do Estado de Minas Gerais (FAPEMIG) [APQ-01945/13]
- FAPEMIG [RED-00010-14]
In the second part of this series of studies, the competitive adsorption of three binary systems Cu2+-Co2+, Cu2+-Ni2+ and Co2+-Ni2+ on a carboxylated cellulose derivative (CTA) was evaluated in binary equimolar (1:1) metal ion aqueous solutions. Bicomponent adsorption studies were developed as a function of contact time and initial metal ion concentration. Bicomponent adsorption kinetic data was modeled by monocomponent kinetic models of pseudo-first- (PFO) and pseudo-second-order (PSO) and a competitive kinetic model of Corsel. Bicomponent adsorption isotherm data was modeled by the ideal adsorbed solution theory (IAST) and real adsorbed solution theory (RAST) models. The monocomponent isotherm models implemented into the IAST were the Langmuir and Sips models, whereas for the RAST model only the Langmuir model was implemented because this model provided the best prediction of the bicomponent isotherm data. The surface of the CTA adsorbent after bicomponent adsorption of metal ions was also examined by SEM-EDX. The effect of one metal ion on the adsorption capacity of another metal ion was discussed in detail with basis on the kinetic and thermodynamics parameters. The selectivity and performance of the CTA adsorbent for the removal of Cu2+, Co2+ and Ni2+ was also evaluated and discussed. (C) 2016 Elsevier Inc. All rights reserved.
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