期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 489, 期 -, 页码 68-75出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2016.08.079
关键词
Pulsed laser ablation in liquids; Kinetic control; Copper nanoparticles; CuO nanoparticles; Zinc nanoparticles; ZnO nanoparticles; Paratacamite; Simonkolleite; Layered zinc hydroxide nitrate; Zincian paratacamite
资金
- NSF CCI Solar Fuels Program [CHE-1305124]
- Arnold and Mabel Beckman Foundation
- National Science Foundation
- Link Energy Foundation
We used pulsed-laser ablation in liquids (PLAL) of Cu or Zn foil targets in water or in aqueous Cu or Zn salt solutions. PLAL in neat water generated mixtures of metal and (thermodynamically preferred) metal oxide nanomaterials, whereas the availability of select dissolved anions predictably led to the fabrication of more complex phase-pure nanominerals. PLAL of Cu foil in aqueous CuCl2 solution produced nanoparatacamite, Cu2Cl(OH)(3), whereas nano-rouaite, Cu-2(NO3)(OH)(3), was formed in aqueous Cu(NO3)(2) and NH4OH solution. Likewise, we synthesized simonkolleite, Zn-5(OH)(8)Cl-2 center dot H2O, or layered zinc hydroxide nitrate, Zn-5(OH)(8)(NO3)(2)center dot H2O, nanoparticles by PLAL of Zn targets in aqueous ablation liquids with added ZnCl2 and NH4OH or Zn(NO3)(2), respectively. Bimetallic zincian paratacamite resulted from PLAL of Cu foil in aqueous Cu and Zn chloride solution. Our results show that kinetic control exceeded thermodynamic product formation during nanosecond ultraviolet PLAL. (C) 2016 Elsevier Inc. All rights reserved.
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