期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 504, 期 -, 页码 731-740出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2017.06.007
关键词
Crosslinked reduced graphene; Reversible Addition Fragmentation Chain Transfer (RAFT); Polymer-graphene composite; Organic-soluble network
资金
- National Science Foundation of China [21574086]
- Nanshan District Key Lab for Biopolymers and Safety Evaluation [KC2014ZDZJ0001A]
- Shenzhen Sci & Tech research grant [ZDSYS201507141105130]
- Shenzhen City Science and Technology Plan Project [JCYJ20140509172719311]
- Shenzhen Science and Technology Innovation Committee [JCYJ20160422143829290]
Here, we demonstrate a novel reversible addition-fragmentation chain transfer agent (RAFT-CTA)modified reduced graphene oxide nanosheets (CTA-rGONSs) by crosslinking rGONSs with a RAFT-CTA via esterification reaction. These nano CTA-rGONSs were used to polymerize a hydrophobic amino acid-based methacrylamide (N-acryloyl-L-phenylalanine methyl ester) monomer with different monomer/initiator ratios. Thermogravimetric analysis showed that the polymer-graphene composites were thermally more stable than GO itself. M-n, of the polymers increased with increasing monomer/initiator ratio, while the polydispersity index decreased, indicating controlled polymerization. The composites were stable in DMF even after two months. (C) 2017 Elsevier Inc. All rights reserved.
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