期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 5, 页码 758-761出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09221h
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资金
- National Research Foundation under the Ministry of Science, ICT & Future Planning of Korea [NRF-2018R1A2A1A05077540]
- US National Science Foundation [CHE-1807152]
- Robert A. Welch Foundation [F-0018]
beta,beta '-Phenylene bridged hexaphyrin[1.0.1.0.1.0] (naphthorosarin), an expanded porphyrin possessing C-3v-symmetry, has been shown to possess unique electronic features. We now report a bimetallic Rh(i)-complex of naphthorosarin retaining 24 pi-antiaromatic characteristics. The two Rh(i) cations reside on opposite sides of the macrocyclic pi-system and are separated at a distance consistent with a possible Rh(i)-Rh(i) metallic bond interaction.
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