期刊
ENERGY STORAGE MATERIALS
卷 25, 期 -, 页码 114-123出版社
ELSEVIER
DOI: 10.1016/j.ensm.2019.10.024
关键词
Flexible energy storage; Mesoporous carbon fiber; MoS2; Sodium-ion hybrid capacitor; Self-discharge
资金
- National Natural Science Foundation of China [51702295]
- Singapore Ministry of Education AcRF Tier 1 [2018-T1-001-228]
- Sino-Singapore International Joint Research Institute (JRI)
Metal-ion hybrid capacitors are regarded as promising power sources for portable electronics because of numerous opportunities in designing the anode/cathode couple to realize high performance and device flexibility. Here we demonstrate our rational design of a porous-fiber network based electrode for quasi-solid-state flexible Na-ion hybrid capacitors. A SiO2-etching approach is deployed to synthesize the freestanding porous carbon nanofiber (PCNF) membrane that is both mechanically robust and light (similar to 1 mg cm(-2)). The PCNF serves as a 3D scaffold for the uniform growth of MoS2@poly(3,4-ethylenedioxythiophene) (PEDOT) core/shell nanosheets. The resultant PCNF@MoS2@PEDOT double core/shell nanofiber electrode not only maintains the intrinsic high-capacity of MoS2 for Na-ion storage, but also renders long-term cyclability and high rate performance. The constructed quasi-solid-state Na-ion hybrid capacitors can tolerate arbitrary bending and folding, and has a much lower self-discharge rate (15 mV h(-1)) compared to symmetric capacitors.
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