期刊
GREEN CHEMISTRY
卷 22, 期 2, 页码 427-432出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc03384j
关键词
-
资金
- National Natural Science Foundation of China [21801076]
- Hunan Provincial Natural Science Foundation of China [2019JJ50415]
- Scientific Research Program of Huaihua [2018N2204]
- Hunan University of Medicine
A simple, efficient and green method for the direct thiolation of aromatic compounds using commercially available sulfonyl chlorides as the sulfur source was developed under metal- and solvent-free conditions. The C-S bond was constructed via direct C-H functionalization of diverse aromatic compounds under an oxygen atmosphere. In this process, various diaryl sulfides were synthesized in moderate to excellent yields. This protocol shows a broad substrate scope and good functional group tolerance. Moreover, a gram-scale experiment was also conducted to prove the prospect of this method for the scale-up synthesis of diaryl sulfides. Mechanistic studies indicate that this procedure probably undergoes a radical pathway.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据