期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 9, 页码 1357-1360出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09407e
关键词
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资金
- Science and Technology Planning Project of Guangdong Province [2017A010103044]
- 100 Young Talents Programme of Guangdong University of Technology [220413506]
- Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province [2016kf07]
A phosphoryl radical-initiated Atherton-Todd-type reaction using air as the radical initiator and CHCl3 as the halogenating reagent for the phosphorylation of alcohols, phenols, and amines has been developed. This novel transformation provides a highly efficient route to important phosphinates, phosphinic amides, and phosphoramidates in up to 99% yield with a broad substrate scope under very mild conditions (48 examples).
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