期刊
ACS APPLIED ENERGY MATERIALS
卷 3, 期 1, 页码 114-121出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.9b01692
关键词
power conversion efficiencies (PCEs); perovskite-based solar cells (PSCs); hole transporting material (HTM); CuSCN; (phenylethyl)ammonium (PEA); [(4-fluorophenyl)etlzyl]ammonium (FPEA)
资金
- QEERI-EPFL
- Qatar National Research Fund (Qatar Foundation) [8-086-1-017]
- PFNM-NM, Solaronix, Aubonne, Switzerland [CTI 25590.1]
We report stable perovskite solar cells having 3D/2D perovskite absorber layers and CuSCN as an inorganic hole transporting material (HTM). (Phenylethyl)ammonium (PEA) and [(4-fluorophenyl)ethyl]ammonium (FPEA) have been chosen as 2D cations, creating thin layers of (PEA)(2)PbI4 or (FPEA)(2)PbI4 on top of the 3D perovskite. The 2D perovskite as an interfacial layer, neutralizes defects at the surface of the 3D perovskite absorber, and can protect from moistureinduced degradations. We demonstrate excellent charge extraction through the modified interfaces into the inorganic CuSCN HTM, with device efficiencies above 18%, compared to 19.3% with conventional spiro-OMeTAD. Furthermore, we show significantly enhanced ambient stability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据