期刊
ACS APPLIED ENERGY MATERIALS
卷 3, 期 1, 页码 377-386出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.9b01641
关键词
photocatalysis; hydrogen evolution; carbon nitride; doping indium
资金
- National Natural Science Foundation of China [21603118, 21872082]
- Young Scholars Program of Shandong University in China [2018WLJH39]
Metal doping is a valid strategy to increase simultaneously photoabsorption, the charge separation efficiency, and thus the photocatalytic activity of polymeric carbon nitride (CN); however, metal elements in groups IIIA-VA in the periodic table are rarely researched in doping CN. Herein, indium (In)-doped CN (In:CN) was first synthesized with In3+ ions inserted in the interlayer, approaching the cavities in the monolayer sheets, and fixed through coordination with nitrogen atoms around them. In:CN exhibits a higher photoabsorption, specific surface area, charge separation and transfer efficiency, and photocatalytic performance in H-2 generation and environmental remediation than bulky CN. The H-2 generation and rhodamine B decomposition rates for In:CN are similar to 2.9 and 4.6 times those for CN, respectively. The apparent quantum yield (420 nm) of In:CN for H-2 production can reach 6.8%. The enhancement in charge separation plays an indispensable role for the photoactivity increase of In:CN, which originates from the generation of an impurity level above the valence band edge in the bandgap because of the In doping, i.e., the In3+-coordination structure works as a hole-capture center. This paper supplies an easy method for CN modification and illustrates the mechanism for In-doping-induced change of the energy band structure, which may guide the preparation of other CN-based photocatalysts with metal doping.
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