期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 12, 页码 1819-1822出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09584e
关键词
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资金
- NSFC [21672033, 21831002, 21801039]
- Jilin Educational Committee [JJKH20190269KJ]
- Fundamental Research Funds for the Central Universities
- Ten Thousand Talents Program
The non-directed hydrosilylation of cyclopropenes with earth-abundant and environmentally benign base metal catalysis was described. This protocol is effective for a wide array of 3,3-disubstituted and 1,2-disubstituted cyclopropenes, and hence provides a facile and straightforward route to synthetically valuable polysubstituted and challenging fully substituted cyclopropylsilanes with high efficiency and diastereoselectivity.
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