期刊
DALTON TRANSACTIONS
卷 49, 期 6, 页码 1847-1853出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04818a
关键词
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资金
- National Natural Science Foundation of China [21171110]
- Research Fund for the Doctoral Program of Higher Education of China [20131404110001]
- Natural Science Foundation of Science and Technology Agency of Shanxi Province [201901D111275, 201801D121047, 201701D121022]
- Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi [2019L0458]
- 1331 Project of Shanxi Province
Two iodobismuthate-based organic-inorganic hybrids, [M(DMSO)(8)][Bi2I9] (M = La (1), Bi (2)), have been successfully designed and synthesized by using solvated metal cations as structure-directing agents (SDAs). 1 displays transient high-temperature thermochromism, which is similar to that of the characteristic low-temperature thermochromic properties of bulk bismuth iodide and iodobismuthate hybrids. In contrast, 2 exhibits distinguishing non-transient thermochromic properties stimulated by the different temperature ranges of the thermal treatments. More importantly, a comparison of the optical inertness of 1 and 2 also reveals novel photochromic behavior. The completely different thermo-/photo-responsive properties of 1 and 2 are mainly ascribed to the different binding abilities of the central metal cations with DMSO molecules, which cause a distinct transformation of the inorganic moiety and consequent modulation of band gaps.
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