期刊
NANOSCALE
卷 12, 期 6, 页码 3614-3622出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9nr07083d
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资金
- European Commission [IRG-246688 Bionanotools]
- CIG project [PCIG14-GA-2013-630978]
- Spanish Ministry of Economy and Competitiveness (MINECO) [BIO2016-77367-C2-1-R, CTQ2014-520456-R, PGC2018-102192-B-I00, RTI2018-101032-J-I00]
- European Research Council [ERC-320441-Chirallcarbon, ERC-2014-CoG-648071-ProNANO, ERC-2015-StG-679001NetMoDEzyme]
- Community of Madrid Government (Photocarbon project) [S2013/MIT-2841]
- Ramon y Cajal grant
- Spanish Ministry of Education
- Basque Government
- European Community [MSCA-IF-2014-EF-661160-MetAccembly]
- Maria de Maeztu Units of Excellence Program from the Spanish State Research Agency [MDM-2017-0720]
- Generalitat de Catalunya [2017 SGR-1707]
Water soluble 2D crystalline monolayers of fullerenes grow on planar assemblies of engineered consensus tetratricopeptide repeat proteins. Designed fullerene-coordinating tyrosine clamps on the protein introduce specific fullerene binding sites, which facilitate fullerene nucleation. Through reciprocal interactions between the components, the hybrid material assembles into two-dimensional 2 nm thick structures with crystalline order, that conduct photo-generated charges. Thus, the protein-fullerene hybrid material is a demonstration of the developments toward functional materials with protein-based precision control of functional elements.
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