期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 8, 期 10, 页码 5171-5185出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta13610j
关键词
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资金
- Program for Changjiang Scholars and Innovative Research Team in University [IRT-13R17]
- National Natural Science Foundation of China [51979103, 51909085, 51679085, 51521006, 51508177, 51579096]
- Fundamental Research Funds for the Central Universities of China [531107050930]
- Funds of Hunan Science and Technology Innovation Project [2018RS3115, 2019RS3012]
- China Postdoctoral Science Foundation [2018M642977]
Metal-free black phosphorus (BP) nanosheets have emerged as a promising photocatalyst. Herein, early transition-metal carbide and nitride (MXene) decorated BP (Ti3C2Tx/TiO2-BP) nanohybrids were constructed by a hydrothermal method, in which TiO2 was produced in the hydrothermal process. The optimized Ti3C2Tx/TiO2-BP nanohybrids exhibited a higher visible-light photodegradation efficiency of rhodamine B (99.09%) and tetracycline hydrochloride (92.70%) pollutants than that of pristine BP (12.75% and 9.35%, respectively). Diverse characterization techniques and density functional theory calculations have revealed that such enhanced photocatalytic performance was due to the synergistic effect of BP and Ti3C2Tx/TiO2, which could markedly improve the stability of BP, increase visible light absorption, prolong the photoexcited electron lifetime, accelerate the photoinduced electron transfer and hinder the electron-hole (e(-)-h(+)) pair recombination. Meanwhile, the mechanism analysis indicated that & x2d9;O-2(-) radicals played a leading role in the photocatalytic process. This study will motivate great interest in using 2D MXenes as co-catalysts to enhance the activity of BP for its applications.
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