Synthesis of Nano-Flakes Ag•ZnO•Activated Carbon Composite from Rice Husk as A Photocatalyst under Solar Light

This study aimed to synthesize Ag center dot ZnO center dot Activated carbon (Ag center dot ZnO center dot AC) composite from rice husk for degradation of dyes. The deposition of Ag and ZnO on AC led to decreasing the surface area and pore volume of Ag center dot ZnO center dot AC composite. In addition, when Ag and ZnO were dispersed on activated carbon, the Ag center dot ZnO flakes became denser and tighter, but the particle size of Ag became smaller from 5 to 7 nm. The photocatalytic ability of Ag center dot ZnO center dot AC composite was evaluated by degradation of Janus Green B (JGB) and compared with that of AC, ZnO, Ag center dot ZnO, and ZnO center dot AC samples. The effects of catalyst dosages, pH values, and initial dye concentrations on photocatalytic degradation were investigated in detail. The Ag center dot ZnO center dot AC composite had a high degradation efficiency of 100% in 60 min, showing the reaction rate of 0.120 min-1 and degradation capacity of 17.8 mg/g within 20 min The photocatalytic performance of the Ag center dot ZnO center dot AC composite was also evaluated by cyclic test and the degradation of other persistent dyes such as Methylene Blue, Tartrazine, Congo Red, and organic compounds (Caffeine and Bisphenol A). Based on the experimental results, the possible destruction route of JGB by the assynthesized Ag center dot ZnO center dot AC composite was suggested. Copyright (C) 2020 BCREC Group. All rights reserved