期刊
DALTON TRANSACTIONS
卷 44, 期 44, 页码 19018-19040出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03359d
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资金
- National University of Singapore [CENGas R-261-508-001-646]
- Singapore Ministry of Education (MOE) [AcRF Tier 1 R-279-000-410-112, Tier 2 R-279-000-429-112]
Metal-organic frameworks (MOFs) are architected via coordination bonds between inorganic metal nodes and organic ligands. They have become emerging advanced porous materials and gained ever-increasing attention in the past decade. In particular, overwhelming studies have been devoted to those hydrostable MOFs which are suggested to be highly promising for industrial applications. UiO-66 is such a unique MOF because of its superior thermal/chemical stability and structural tunability. However, its repeatable, green, and scale-up synthesis remains a challenge for its commercialization and implementation in industrial applications. This perspective mainly summarises the recent development in the synthesis of UiO-66-type MOFs and their related composites. From a scale-up viewpoint, we also present some important advances in the batch and continuous reactor synthesis toward their massive production (226 references).
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