期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 167, 期 2, 页码 -出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/ab69fa
关键词
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资金
- National Natural Science Foundation of China [51301117, 11502158, 51671140]
- International Cooperation Project Foundation of Shanxi Province China [201603D421037, 2015081053]
- Top Young Academic Leaders of Shanxi
- 1331 project Key Innovation Teams of Shanxi Province
- Higher School Science and Technology Innovation Project Foundation of Shanxi Province China [2016128]
- Shanxi Scholarship Council of China [2015-034]
- NSF [CMMI-1634540]
In this work, we develop an approach to synthesize a nanoscale structure with Sb nanocrystals and polypyrrole nano-network (Sb@ppy NNW) from the reduction of SbCl3 and the polymerization and crosslinking of pyrrole. The Sb@ppy NNW exhibits excellent electrochemical characteristics with incessant conduction paths for fast transfer of electrons, short paths for fast diffusion/migration of ions and large contact area between active material and electrolyte for the storage of Na/Li. The Sb@ppy NNW is used as active material in the working electrode for lithium-ion half cells and sodium-ion half cells. The sodium-ion half cells possess excellent cycling stability with a high specific capacity of 510 mA h g(-1) at a current density of 100 mA g(-1) and 463 mA h g(-1) after 100 cycles at a current density of 500 mA g(-1), and superior rate performance with a specific capacity of 635.6 mA h g(-1) even at a current density of 1600 mA g(-1). The specific capacities for the lithium-ion half cells are 660 mA h g(-1) after 100 cycles at a current density of 100 mA g(-1) and 635.6 mA h g(-1) even at a current density of 1600 mA g(-1). (C) 2020 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited.
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