期刊
SN APPLIED SCIENCES
卷 2, 期 3, 页码 -出版社
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s42452-020-2205-6
关键词
Co-HKUST; Asymmetric supercapacitor; Cycling performance; Energy density
资金
- National Natural Science Foundation of China [21301002]
- University Natural Science Research Project of Anhui Province [KJ2018A0107]
In this work, we first successfully loaded the MOF structure Co-HKUST nanobundles on a foamed nickel without adding any binder. The Co-HKUST is a pseudo-capacitive material with excellent electrochemical performance as a unique energy storage material. As an electro-active material, such cobalt-based MOF exhibits superior pseudo-capacitive behavior in the KOH aqueous electrolyte with a high specific capacitance of 578.6 F g(-1) at 1 A g(-1), and the specific capacitance remains 452.3 F g(-1) when the current density increased to 10 A g(-1) with a good rate performance (78.2%). Meanwhile, the cycle retention rate of the Co-HKUST is 88.7% after 1000 cycles at 7.5 A g(-1). The two-electrode asymmetric supercapacitor (ASC) device is also assembled in this work. The specific capacitance of Co-HKUST//AC ASC is 200.5 F g(-1) at 1 A g(-1). Though 5000 cycles at 5 A g(-1), only 8.2% of the capacitance is lost. Energy density of asymmetric Co-HKUST//AC device can reach 71.35 Wh kg(-1) at 1 A g(-1) with a power of 809.9 W kg(-1). More interestingly, even if the current density increased to 10 A g(-1), the energy density maintains 44 Wh kg(-1) at power density of 8.5 kW kg(-1). The above test results can fully show that the synthesized Co-HKUST material is a promising energy storage material.
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