期刊
DALTON TRANSACTIONS
卷 44, 期 29, 页码 12976-12980出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01667c
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资金
- National Natural Science Foundation of China [21261006]
- Natural Science Foundation of Guizhou province [2012/2115]
- Graduate Innovation Fund of Guizhou University [2014069]
Imidazole was introduced into the channels of the metal-organic framework UiO-67 using an evaporation method. The imidazole@UiO-67 composite presents a high proton conductivity of 1.44 x 10(-3) S cm(-1) at 120 degrees C under anhydrous conditions. With a low activation energy at high temperatures (0.36 eV), the hybrid material can be regarded as a superionic conductor.
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