期刊
GREEN CHEMISTRY
卷 22, 期 4, 页码 1125-1128出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc04260a
关键词
-
资金
- National Science Foundation [CHE-1554906]
A highly efficient, room temperature double hydroboration of nitriles under transition metal-free and solvent-free conditions is reported. Sodium triethylborohydride is used as a catalyst and yields up to 99% are disclosed. Mechanistic studies reveal the reaction proceeds in a stepwise manner with initial formation of a boryl-imine which undergoes a second hydroboration to afford a diborylated amine product.
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