期刊
DALTON TRANSACTIONS
卷 49, 期 8, 页码 2610-2615出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04637b
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资金
- US National Science Foundation [CHE-1900500]
- PSC-CUNY [61321-0049, 62154-0050]
- Seed grant from the Office for Advancement of Research
- PRISM program at John Jay College, the City University of New York
Reductive catalysis with earth-abundant metals is currently of increasing importance and shows potential in replacing precious metal catalysis. In this work, we revealed catalytic hydroboration and hydrosilylation of ketones and aldehydes achieved by a structurally defined manganese(ii) coordination polymer (CP) as a precatalyst under mild conditions. The manganese-catalysed methodology can be applied to a range of functionalized aldehydes and ketones with turnover numbers (TON) of up to 990. Preliminary results on the regioselective catalytic hydrofunctionalization of styrenes by the Mn-CP catalyst are also presented.
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