期刊
DALTON TRANSACTIONS
卷 44, 期 5, 页码 2122-2131出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03079f
关键词
-
资金
- National Science Foundation (NSF) [CHE-1054286, CHE-1361178]
- Donors of the American Chemical Society Petroleum Research Fund [54228-ND1]
- DOD-MURI program under AFOSR Award [FA9550-10-1-057]
- NSF [CHE-1308652]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1308652] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1361178] Funding Source: National Science Foundation
The synthesis, electrochemical activity, and relative photodecomposition rate is reported for four new Mn(I) N-heterocyclic carbene complexes: [MnX(N-ethyl-N'-2-pyridylimidazol-2-ylidine)(CO)(3)] (X = Br, NCS, CN) and [MnCN(N-ethyl-N'-2-pyridylbenzimidazol-2-ylidine)(CO)(3)]. All compounds display an electrocatalytic current enhancement under CO2 at the potential of the first reduction, which ranges from -1.53 V to -1.96 V versus the saturated calomel electrode. Catalytic CO production is observed for all species during four-hour preparative-scale electrolysis, but substantial H-2 is detected in compounds where X is not Br. All species eventually decompose under both 350 nm and 420 nm light, but cyanide substituted complexes (X = CN) last significantly longer (up to 5x) under 420 nm light as a result of a blue-shifted MLCT band.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据