期刊
DALTON TRANSACTIONS
卷 49, 期 7, 页码 2234-2243出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04176a
关键词
-
资金
- National Natural Science Foundation of China [21671185]
A new oxofluoride Co15F2(TeO3)(14) has been prepared by optimized hydrothermal synthesis involving a complex mineralization process. The crystal structure consists of a three-dimensional network of CoO5(O,F) octahedra, distorted CoO5 square pyramids, TeO3 trigonal pyramids and grossly distorted TeO3+3 octahedra, which are linked by sharing corners and edges. The Te(iv) lone pairs are accommodated within novel pyritohedron-shaped [(TeO3)(14)](28-) units. This special framework provides a much larger free space that allows Te atoms to vibrate with a large amplitude, which leads to extremely low lattice thermal conductivity. Magnetic susceptibility data for Co15F2(TeO3)(14) show antiferromagnetic ordering below 9.6 K with a substantial orbital component to the effective magnetic moment. An S = 3/2 honeycomb-like spin network was carefully analyzed by experimental techniques and first principles calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据