期刊
DALTON TRANSACTIONS
卷 44, 期 7, 页码 3326-3341出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03318c
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资金
- JSPS KAKENHI [25870293]
- JST A-STEP [AS251Z02999M]
The synthesis and the solution/solid-state fluorescence properties of pyrimidine-based monoboron complexes differing in terms of the substituents [either two fluorine atoms (BF2 complex) or two phenyl groups (BPh2 complex)] on the boron atom are reported herein. Unrestricted C-Ar intramolecular rotation in the non-, trifluoromethyl-, and cyano-substituted derivatives resulted in negligible fluorescence in solution. On the other hand, methoxy-and dimethylamino-substituted analogues caused the restriction of the C-Ar intramolecular rotation and consequently resulted in relatively strong fluorescence in solution. The non-, trifluoromethyl-, and cyano-substituted derivatives showed a pronounced aggregation-induced emission enhancement effect. Dimethylamino-substituted derivatives exhibited solvatochromism in the fluorescence spectra. Substitution with BPh2 effectively enhanced the fluorescence quantum yield compared to the corresponding BF2 complexes in the solid-state.
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