期刊
DALTON TRANSACTIONS
卷 44, 期 48, 页码 21032-21040出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04058b
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资金
- European Research Council
- Fonds der Chemischen Industrie
Dimethylbenzofulvene adds Piers' borane [HB(C6F5)(2)] at the indene double bond to give a mixture of regioisomeric boranes 8a,b. Subsequent isomerization under equilibrium conditions gives the isopropyl substituted 1H and 3H borylindenes 10a,b. Their treatment with the bulky LiTMP base under frustrated Lewis pair conditions resulted in a clean deprotonation reaction to give the borata-alkene 14. Its X-ray crystal structure analysis indicated a pronounced B=C double bond character and thus a borata-benzofulvene description. The borata-alkene underwent (probably stepwise) [4 + 2] cycloaddition reactions with chalcone derivatives and a formal [6 + 2] cycloaddition with phenylmethylketene. Many products and derivatives were characterized by X-ray diffraction.
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