期刊
DALTON TRANSACTIONS
卷 44, 期 40, 页码 17453-17461出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03442f
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资金
- Science and Engineering Research Board (SERB), New Delhi
- University of Delhi
- UGC, New Delhi
- CSIR, New Delhi
This work presents synthesis and characterization of trinuclear {Co2+-Co3+-Co2+} and {Co2+-Fe3+-Co2+} complexes with accessible peripheral Co(II) ions. Both trinuclear complexes function as efficient reusable heterogeneous catalysts for the selective reduction of assorted nitro compounds to the corresponding amines. The mechanistic investigations suggest the involvement of a Co(II)-Co(I) cycle in the catalysis.
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