期刊
DALTON TRANSACTIONS
卷 44, 期 19, 页码 8950-8958出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00684h
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The anisole-substituted silyl-amide anion, [N(SiMe2{C6H4-2-OMe})(2)](-) (L), has been used as a pincer-type ligand in coordination chemistry. X-ray diffraction data for the lithium salt shows a trimetallic structure consisting of two equivalents of Li(L) that sequester a molecule of LiCl. The potassium salt K(L) is dimeric in the solid-state with bridging amide ligands. Each structure shows chelation of both O-donor groups to the electropositive metal. In contrast, the titanium compound Ti(L)Cl-3 is four-coordinate with a monodentate amide. The zirconium compound Zr(L)(2)Cl-2 is monometallic with a six-coordinate metal and two N,O-bidentate amides.
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