期刊
CHEMICAL SOCIETY REVIEWS
卷 49, 期 5, 页码 1487-1516出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cs00539k
关键词
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资金
- University of Science and Technology
- National Natural Science Foundation of China [21925111, 21790333, 21702197, 21672199]
Reductive elimination is a crucial bond-forming elementary reaction in various transition-metal mediated reactions. Apart from the well-developed classic reductive elimination, the non-classic reductive elimination occurring between a covalent ligand and a dative ligand, which has been known for over 50 years, has gradually attracted much attention from the organic community. By avoiding p pi-d pi repulsion between the filled metal d-orbital and the filled ligand p-orbital and forming a cationic-type molecule, non-classic reductive elimination could facilitate many catalytic reactions that were difficult to be realized via classic reductive elimination. In this review, transition-metal catalyzed C-P, C-S, C-N, and C-C bond-forming reactions with non-classic reductive elimination as the key elementary step are summarized.
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