期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 18, 期 10, 页码 1987-1993出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ob00048e
关键词
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资金
- National Natural Science Foundation of China [21971174, 21772137, 21542015, 21672157]
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201708]
- Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions, Soochow University [16KJA150002]
A highly efficient iron(iii) chloride-promoted cyclization between alpha,beta-alkynic tosylhydrazones and diselenides to form a 4-(arylselanyl)-1H-pyrazole skeleton is studied. This reaction forms C-N and C-Se bonds in one step by utilizing inexpensive iron(iii) chloride instead of expensive transition metal additives. This strategy features easily synthesized substrates, mild reaction conditions and high tolerance to functional groups.
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