4.7 Article

Manipulating the surface composition of Pt-Ru bimetallic nanoparticles to control the methanol oxidation reaction pathway

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 16, 页码 2419-2422

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09423g

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资金

  1. National Key Research and Development Program of China [2016YFB0101202]
  2. National Natural Science Foundation of China [91534205, 21436003, 21576031, 21776023]
  3. Fundamental Research Funds for the Central Universities [2018CDXYHG0028]

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The rational manipulation of reaction intermediates is crucial for achieving high-performance heterogeneous catalysis. Herein, using in situ Fourier transform infrared-diffuse reflection (FTIR) analysis, we report that the methanol oxidation reaction (MOR) intermediates can be controlled by precisely tuning the location and content of Ru on the Pt-Ru alloy surface.

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