期刊
DALTON TRANSACTIONS
卷 44, 期 16, 页码 7109-7113出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00346f
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资金
- Leverhulme Trust [RPG-2012-460]
- UK EPSRC for Core Capability [EP/K039547/1]
- Engineering and Physical Sciences Research Council [EP/K039547/1] Funding Source: researchfish
- EPSRC [EP/K039547/1] Funding Source: UKRI
Two dysprosium complexes, [(C5H4Me)(2)Dy(L-1)] (3) and [(L-1)Dy-(mu-Cl)(3){Li(tmeda)}](2) (4), with amino-functionalized pentadienyl ligands L-1 are described. Crystallographic studies of 3 and 4 show that the pendant amino group influences the pentadienyl conformation and the ligand hapticity. Electronic structure calculations reveal that L-1 has a strong influence on the orientation of the main magnetic axis of the ground Kramers doublets in 3 and 4.
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