期刊
DALTON TRANSACTIONS
卷 44, 期 20, 页码 9349-9352出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01322d
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资金
- National Research Foundation of Korea (NRF) grant - Korea government (MSIP) [2011-0016303, 2009-0053318]
- MEST
- POSTECH
Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e. g., that of the surface is anisotropic, whereas that of the interior is isotropic.
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