期刊
DALTON TRANSACTIONS
卷 44, 期 16, 页码 7548-7553出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00521c
关键词
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资金
- EU COST project MP1202 [OC-2011-2-10820]
- Generalitat de Catalunya [2014SGR377]
- [RyC-2012-11588]
The preparation of copper(II) one-dimensional MOFs using an eco-efficient method is reported here. This method is based exclusively on using supercritical CO2 as a solvent, without the addition of any other additive or co-solvent. Neutral acetylacetonate copper complexes and two linear linkers, namely, the bidentate 4,4'-bipyridine and 4,4'-trimethylenedipyridine molecules, were reacted under compressed CO2 at 60 degrees C and 20 MPa for periods of 4 or 24 h. The success achieved in the synthesis of the different studied 1D-MOFs was related to the solubility of the reagents in supercritical CO2. The reaction yield of the synthesized coordination polymers via the supercritical route was close to 100% because both the reactants were almost completely depleted in the performed experiments.
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