期刊
DALTON TRANSACTIONS
卷 44, 期 7, 页码 3251-3258出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03010a
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资金
- Deutsche Forschungsgemeinschaft (DFG)
- COST [CM 1003]
- CAU Kiel
A new tridentate N-donor ligand and its corresponding copper(I) complex have been synthesized to investigate the tyrosinase-like aromatic hydroxylation of an attached phenol. The results of the oxygenation reactions are compared to related systems having attached phenyl and catechol groups, respectively. The title complex is the first system mediating the monooxygenation of a phenol in the absence of an external base.
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