期刊
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY
卷 22, 期 5, 页码 713-725出版社
SPRINGER
DOI: 10.1007/s00775-017-1438-3
关键词
Iron complex; Porphyrin; Pyrene; Electrochemistry; CO2 Reduction
资金
- Japan Society for the Promotion of Science [16H04125, 15H05480, 26620160]
- ACT-C, JST
- [15H00889]
- Grants-in-Aid for Scientific Research [15H00889, 15H05480, 26620160, 16H04125] Funding Source: KAKEN
The construction of molecular catalysts that are active toward CO2 reduction is of great significance for designing sustainable energy conversion systems. In this study, we aimed to develop catalysts for CO2 reduction by introducing aromatic substituents to the meso-positions of iron porphyrin complexes. Three novel iron porphyrin complexes with pi-expanded substituents (5,10,15,20-tetrakis(pyren-1-yl) porphyrinato iron(III) chloride (Fe-Py)), pi-extended substituents (5,10,15,20-tetrakis((1,1'-biphenyl)-4-yl) porphyrinato iron(III) chloride (Fe-PPh)) and pi-expanded and extended substituents (5,10,15,20-tetrakis(4-(pyren-1-yl) phenyl) porphyrinato iron(III) chloride (Fe-PPy)) were successfully synthesized, and their physical properties were investigated by UV-vis absorption spectroscopy and electrochemical measurements under Ar in comparison with an iron complex with a basic framework, 5,10,15,20-tetrakis(phenyl) porphyrinato iron(III) chloride (Fe-Ph). Moreover, the catalytic activity of the complexes was studied by electrochemical measurements under CO2, and it is found that the complex with the pi-expanded substituents exhibits the highest activity among these complexes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据