期刊
ACTA CHIMICA SLOVENICA
卷 67, 期 1, 页码 130-136出版社
SLOVENSKO KEMIJSKO DRUSTVO
DOI: 10.17344/acsi.2019.5286
关键词
Hydrazone; Vanadium complex; Molybdenum complex; Crystal structure; Catalytic property
资金
- special funds of key disciplines construction from Guangdong and Zhongshan cooperating
- Guangdong Pharmaceutical University Cosmetics Talent Practice Teaching Base
N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide (H2L) was used to prepare oxidovanadium(V) complex [VOL(OEt)(MeOH)] (1) and dioxidomolybdenum(VI) complex [MoO2L(OH2)]center dot[MoO2L(EtOH)] (2). The complexes were characterized by IR, UV-Vis, NMR spectroscopy, and single crystal X-ray diffraction. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydroperoxide as oxidant.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据