期刊
DALTON TRANSACTIONS
卷 44, 期 32, 页码 14293-14303出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01642h
关键词
-
资金
- Institute for Advanced Studies in Basic Sciences (IASBS) Research Council
- Iran National Science Foundation (INSF-Grant) [93020713]
A new polymer containing phosphorus and nitrogen ligands was successfully synthesized, characterized and used for the stabilization of highly monodispersed palladium nanoparticles having an average diameter of 2-3 nm. The thermally stable heterogeneous catalyst was successfully applied in Suzuki-Miyaura and copper-free Sonogashira-Hagihara coupling reactions of aryl halides under low palladium loading conditions. Reactions were proceeded in neat water without using any organic co-solvents. The catalyst was successfully recycled for the sample Suzuki-Miyaura reaction nine consecutive times with small drop in catalytic activity.
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