期刊
DALTON TRANSACTIONS
卷 44, 期 28, 页码 12473-12483出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01617g
关键词
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资金
- American Chemical Society Petroleum Research Fund
- [NSF-1360347]
- [NSF GRFP DGE-0829517]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1360347] Funding Source: National Science Foundation
Heteroleptic phosphines (R2PR1) are a class of essential ligands for inorganic and organometallic chemistry. However, the syntheses of these phosphines are often fraught with laborious synthetic hurdles. Consequently, a renewed interest in innovative synthetic methods to access heteroleptic phosphines is emerging. This Perspective presents an overview of modern synthetic approaches to heteroleptic phosphines as well as a discussion of the strengths and limitations of these synthetic methods. A major emphasis is placed on simple and direct routes to phosphines and significant synthetic innovations for P-C bond-forming reactions.
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