期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 135, 期 1, 页码 -出版社
WILEY
DOI: 10.1002/app.45650
关键词
membranes; oil and gas; separation techniques
资金
- Research center for CO2 capture (RCCO2C)
- Universiti Teknologi PETRONAS
Asymmetric polysulfone (PSF) membrane was developed and modified to PSF/polydimethylsiloxane (PSF/PDMS) composite membrane by dip coating technique. Effect of PDMS coating time on membrane properties was examined by scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, attenuated total reflectance-Fourier transform infrared, and water contact angle. The increase in PDMS coating time resulted in a decrement in the thermal strength of PSF membrane. Surface contact angle values revealed that increase in PDMS coating time had increased the surface hydrophobicity in membranes. CO2/CH4 separation performance of membranes was evaluated, and an increase in CO2/CH4 ideal selectivity was observed with the increase of PDMS coating time. At feed pressure of 10 bar, the selectivity of PSF has increased up to 65% after dip coating with PDMS for 30 min. Modification of polymeric membrane into composite membrane provided a way forward towards the enhancement of gas separation performance in polymeric membranes. (C) 2017 Wiley Periodicals, Inc.
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