期刊
GREEN CHEMISTRY
卷 22, 期 3, 页码 651-656出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc04137k
关键词
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资金
- Key Technology R&D Program of Shandong Province [2019GGX102075]
- Open Projects of the State Key Laboratory of Physical Chemistry of the Solid Surface (Xiamen University) [201808]
- 13th-Five Key Project of the Chinese Academy of Sciences [Y7720519KL]
- Royal Society (UK) [NAF\R2\180695]
An ultrafine Ni2P (a metal-rich interstitial phosphide compound) nanoparticles with a narrow size distribution homogeneously dispersed on N,P-codoped carbon was developed for efficient synthesis of alkynyl thioethers via base- and ligand-free cross-dehydrogenative coupling (CDC) of terminal alkynes and thiols using atmospheric air as the oxidant under mild conditions. A remarkable catalytic performance with good functional group compatibility, broad substrate scope and high stability is accomplished. Pyridinic N atoms are identified as basic sites for facilitating the activation of terminal alkynes via hydrogen bonding interactions and play a key role in the success of this base- and ligand-free CDC reaction.
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