期刊
DALTON TRANSACTIONS
卷 44, 期 23, 页码 10614-10620出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt02875a
关键词
-
资金
- 973 project [2014CB932103]
- National Natural Science Foundation of China [21290172, 21371032, 21101025]
A new organic-inorganic hexagonal perovskite-type compound with the formula ABX(3), thiazolium tribromocadmate(II) (1), in which thiazolium cations are situated in the space between the one-dimensional chains of face-sharing CdBr6 octahedra, has been successfully synthesized. Systematic characterizations including differential scanning calorimetry measurements, variable-temperature structural analyses, and dielectric measurements reveal that it undergoes two structural phase transitions, at 180 and 146 K. These phase transitions are accompanied by remarkable dielectric relaxation and anisotropy. The thiazolium cations remain orientationally disordered during the two phase transition processes. The origins of the phase transitions at 180 and 146 K are ascribed to the slowing down and reorientation of the molecular motions of the cations, respectively. Moreover, the dielectric relaxation process well described by the Cole-Cole equation and the prominent dielectric anisotropy are also connected with the dynamics of the dipolar thiazolium cations.
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