期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 28, 页码 3971-3974出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09990e
关键词
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资金
- Danish Council for Independent Research, Technology and Production [4181-00462, 9041-00226B]
- NordForsk [81942]
- Nordic Neutron Science Program [81942]
- Sichuan University [YJ201914]
- National Natural Science Foundation of China [21975168]
- KIST Institutional Program [2E29630]
- National Research Foundation of Korea [2E29630, 2E30211] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Hemiammine lithium borohydride, LiBH4 center dot 1/2NH(3), is characterized and a new Li+ conductivity mechanism is identified. It exhibits a Li+ conductivity of 7 x 10(-4) S cm(-1) at 40 degrees C in the solid state and 3.0 x 10(-2) S cm(-1) at 55 degrees C after melting. The molten state of LiBH4 center dot 1/2NH(3) has a high viscosity and can be mechanically stabilized in nano-composites with inert metal oxides and other hydrides making it a promising battery electrolyte.
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