期刊
JOURNAL OF POLYMER SCIENCE
卷 58, 期 9, 页码 1325-1337出版社
WILEY
DOI: 10.1002/pol.20190255
关键词
carbon dioxide; amino-functionalized poly(propylene carbonate); SalenCo((III))Cl; PPNCl; hydrophilicity; terpolymerization
资金
- Pujiang Talent Projects [16PJD016]
New strategies for synthesis of amino-functionalized poly(propylene carbonate) (PPC) were applied by terpolymerization of carbon dioxide, propylene oxide, with (a) N-(2,3-epoxypropyl)-2-phthalimide (Monomer A)/N-(2-oxiranylmethyl)-1 or (b) N-(2-oxiranylmethyl)-1,1-dimethylethyl ester (Monomer B) over SalenCo((III))Cl/PPNCl catalysts system, followed by the removal of the respective protecting groups. The SalenCo((III))Cl presented high activity and yielded the terpolymer with high polycarbonate selectivity, carbonate linkage content, as well as high head-to-tail stereoregularity (>99%). In terpolymerization, the Monomer A contents in PPC-Pht were easily regulated up to 12.0 mol%. However, the protecting groups could not be completely removed because of the degradation of PPC-NH2-A during the deprotection process. Meanwhile, when terpolymerization with Monomer B, PPC-butoxy carbonyl was obtained varied the Monomer B contents from 1.3 to 4.5 mol%, and could be transformed completely into the amino-functionalized PPC-NH2-B without significant backbone degradation. The contact angles of the functionalized PPC-NH(2)s prepared by two strategies showed the expected increase in hydrophilicity with the increasing content of amino entities.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据