期刊
BATTERIES & SUPERCAPS
卷 3, 期 8, 页码 672-697出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/batt.201900177
关键词
analytical techniques; cathodes; electrode-electrolyte interface; lithium-ion batteries; positive electrodes; solid-electrolyte interphase; surface layer; solid permeable interphase; cathode-electrolyte interphase
The operating potentials of the Li-ion batteries active materials usually exceed the stability window of the electrolyte, leading to its irreversible reduction or oxidation. Often, as an effect of these side reactions, a surface layer is deposited onto the electrodes' materials. These surface layers play a pivotal role on the battery performance, rate capability, irreversible charge losses, and safety. Despite their importance, such interphases are difficult to analyse because of their small thickness and sensitive chemical composition. With this review, the authors intend to describe the already established analytical tools for the analysis of the interphase layers formed at the electrodes' surface in Li-ion batteries, together with the novel, unconventional ones under current development, focusing on the strengths and weak points of each technique. Particular attention will be given to the surface layers formed onto the positive electrodes through a summary of their current understanding. This is of main importance since understanding the interphase at the positive electrode side could enable the next generation of high energy Li-ion batteries.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据