期刊
NEW JOURNAL OF CHEMISTRY
卷 44, 期 12, 页码 4869-4876出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9nj06165g
关键词
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资金
- NSFC [21774045]
- JLU Science and Technology Innovative Research Team [2017TD-06]
N-Doped hollow Fe3O4/Pd@C nanocontainer (NC) composites, involving the loading of magnetic Fe3O4 and subminiature noble metal Pd nanoparticles (NPs), were prepared. The synthetic process involves the decomposition of Fe3O4/Pd2+@ZIF-8 and the polymerization of dopamine simultaneously via a Chelation Competition Induced Polymerization process, forming hollow polymer NCs. Then, they were carbonized into Fe3O4/Pd@C NCs. The structure and composition of the as-prepared nanocontainers were characterized. The catalytic performance of the Fe3O4/Pd@C NC composites was studied by the reduction of 4-nitrophenol with NaBH4 as a reducing agent. The reaction rate constant was calculated according to the pseudo-first-order reaction equation. It was found that subminiature Pd NPs were obtained, and the coordination interaction between Pd and N in PDA prevented Pd NPs from aggregating during high-temperature calcination, resulting in a high k value. Besides the good catalytic properties, high stability of Fe3O4/Pd@C NCs was also confirmed.
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