期刊
JOURNAL OF APPLIED ELECTROCHEMISTRY
卷 47, 期 3, 页码 405-415出版社
SPRINGER
DOI: 10.1007/s10800-017-1047-4
关键词
Thick electrodes; Numerical modeling; Energy/power density; Li-ion depletion
资金
- U.S. Department of Energy - Office of Energy Efficiency and Renewable Energy Vehicle Technologies Office Applied Battery Research subprogram [DE-AC05-00OR22725]
Increasing electrode thickness, thus increasing the volume ratio of active materials, is one effective method to enable the development of high energy density Li-ion batteries. In this study, an energy density versus power density optimization of LiNi0.8Co0.15Al0.05O2 (NCA)/graphite cell stack was conducted via mathematical modeling. The energy density was found to have a maximum point versus electrode thickness (critical thickness) at given discharging C rates. The physics-based factors that limit the energy/power density of thick electrodes were found to be increased cell polarization and underutilization of active materials. The latter is affected by Li-ion diffusion in active materials and Li-ion depletion in the electrolyte phase. Based on those findings, possible approaches were derived to surmount the limiting factors. The improvement of the energy-power relationship in an 18,650 cell was used to demonstrate how to optimize the thick electrode parameters in cell engineering.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据