期刊
JOURNAL OF ANALYTICAL CHEMISTRY
卷 72, 期 1, 页码 83-86出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1061934816110022
关键词
formaldehyde in urine; o-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine; headspace gas-chromatographic analysis
资金
- integration program Fundamental Research and Breakthrough Technology as the Basis for the Advanced Development of the Baikal Region and Its Inter-regional Relations [3.4]
A method is proposed for determining formaldehyde by headspace gas chromatography using an o-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) derivatizing agent. Formaldehyde in urine was derivatized to o-(pentafluorobenzyl)oxime and extracted by heating an urine sample with PFBHA in a sealed vial. Gas-chromatographic analysis of the headspace was performed in the temperature-programmed mode using an HP-5 capillary column with a flame ionization detector. The limit of detection is 3.5 mu g/L. The accuracy of the procedure, equivalent to an extended relative uncertainty, does not exceed 21%. The examination of the procedure using urine samples of the population of the Irkutsk region has shown that the regional reference levels of formaldehyde concentration are in the range 44-83 mu g/L.
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