期刊
RSC ADVANCES
卷 10, 期 21, 页码 12192-12196出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra01927e
关键词
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资金
- National Science Foundation of China [21861030]
- Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region [NJYT-17-A22]
- Research Innovation Fund of Inner Mongolia Normal University [CXJJS18075]
The palladium catalyzed aldehyde directed acetoxylation of C(sp(3))-H bonds was realized by a transient directing group approach for the first time. Crucial to the successful outcome of this reaction is the dual role of acetohydrazide as a directing group for the catalytic C(sp(3))-H activation process and as a protecting group for the CHO functional group. The applicable methodology exhibits good functional group tolerance and occurs readily under mild conditions.
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